Redox and Electrode Potentials

Redox Reactions

OILRIG: Oxidation is loss of electrons and increase in oxidation number. Reduction is gain of electrons and decrease in oxidation number.  Redox: A reaction where both oxidation and reduction take place.  Oxidation Number: A measure of the number of electrons that...

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Manganate (VII) Redox Titrations

Redox titrations similar to acid- base titration.  If don’t know which way round colour changes, look at table to see what’s added.  Manganate (VII) Titrations: Potassium manganate (VII) KMnO4 under acidic conditions. Potassium manganate can be replaced by other...

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Iodine/ Thiosulfate Redox Titrations

Iodine/ Thiosulfate Titrations: Oxidising agent must first oxidise I- ions to I2. Then thiosulfate ions S2O3 2- are oxidised and iodine reduced. Amount of iodine can be determined. As well iodine, other oxidising agents can be determined such as chlorate ions ClO- in...

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Electrode Potentials

Voltaic Cell: A voltaic cell is a type of electrochemical cell, which converts chemical energy to electrical energy. Chemical energy from movement of electrons, so use redox reactions as they transfer electrons.  Half Cell: A half-cell contains species present in...

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Predictions from Electrode Potentials

Predicting Feasibility: Can predict feasibility of reaction from standard electrode potentials. A reaction takes place when the one being reduced (and on left) has a more positive E o value than one being oxidised (and on right).  This works as higher E o value means...

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Storage and Fuel Cells

Modern Cells and Batteries: Modern cells and batteries based on two electrodes with different electrode potentials. Three main times of cells- primary, secondary and fuel cells.  Primary Cells: Primary cells are non- rechargeable. Electricity is produced by oxidation...

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