The Haber Process

The Haber Process

The Haber process is used to make ammonia NH3

 

Uses of ammonia include:

  • Making fertilisers
  • Making nitric acid
  • Making nylon

 

The equation for the reaction is:

N2 + 3H2       2NH3                               ∆H = -92 kJ mol-1

 

  • The forward reaction would be favoured by a low temperature because the forward reaction is exothermic (so lowering the temperature would cause the reaction to make more NH3 to heat things up abit more). 450ºC isn’t a low temperature. It is however, a compromise temperature, because if the temperature was made to be low, the reaction would be so slow that it would take a very long time to produce much ammonia.
  • Pressure is also another compromised. Because the forward reaction has less molecules than the back reaction (2 molecules of NH3 as opposed to 1 N2 and 3 H2 molecules), the forward reaction would be favoured by a high pressure. 200 atm is high, but anything higher would be extremely expensive.
  • The iron catalyst speeds the reaction up but has no effect on the equilibrium. However, if the catalyst wasn’t used, the reaction would be too slow.