10.2Reactivity series

Reactivity series

K – Potassium

Na – Sodium

Ca – Calcium

Mg – Magnesium

Al – Aluminium

C – Carbon

Zn – Zinc

Fe – Iron

Pb – Lead

H – Hydrogen

Cu – Copper

Ag – Silver

Au – Gold

Everything above Hydrogen can displace hydrogen from its acid, and hydrogen cannot reduce their oxides. Metals above carbon, their oxides cannot be reduced by carbon. An element can displace an other element from it’s oxide if it is more reactive e.g. copper oxide + zinc → copper + zinc oxide. More reactive metals will react with cold water, and

less reactive will react slowly or not react with steam.

(Paper 6: copper (II) oxide is a black solid)

The elements further up the reactivity series form more stable compounds and have a greater desire to exist in a compound than as an element, so:

-metals will displace a less reactive metal from its oxide or…

displace a less reactive metal from a salt in a solution. Thermal decomposition:

Metal hydroxide → (heat) → metal oxide + water

This does not apply to potassium and sodium. It happens faster, the further you go down the reactivity series. All nitrates decompose on heating, but don’t all form the same products.

Potassium or sodium nitrate → (heat) → potassium or sodium nitrite + oxygen Metal nitrate (except K and Na) → (heat) → metal oxide + nitrogen dioxide + oxygen

Aluminium seems unreactive because it naturally forms an oxide layer which protects it.