8.3.1 Flame tests
Positive Ion (Cation) | Test | Positive Result |
Lithium, Li+ | Flame Test
|
Crimson Red |
Sodium, Na+ | Yellow | |
Potassium , K+ | Lilac | |
Calcium, Ca2+ | Orange-Red | |
Copper, Cu2+ | Green |
Why should wire be clean when used for a flame test? (1)
- To prevent contamination that gives an accurate result
What are the properties that wire must have for a flame test? (2)
- High melting point
- Unreactive
Why is it not possible to tell from the flame test that both ions are present in low concentration? (1)
Colours mask each other
8.3.2 Metal hydroxides
Positive Ion (Cation) | Test | Positive Result |
Zinc, Zn2+ |
Precipitation
A precipitate will appear depending on the ion in the solution |
White |
Calcium, Ca2+ | White | |
Aluminium, Al3+ | White, redissolves in excess NaOH | |
Copper (II), Cu2+ | Blue | |
Iron (II), Fe2+ | Green | |
Iron (III), Fe3+ | Brown | |
Magnesium, Mg2+ | White |
8.3.3 Carbonates
8.3.4 Halides
8.3.5 Sulfates
Negative Ion (Anion) | Test | Positive Result |
Carbonate, CO32- |
|
Bubbles of CO2 gas will produce → turn limewater milky |
Chloride, Cl- |
Precipitation
|
White precipitate |
Bromide, Br- | Cream precipitate | |
Iodide, I- | Yellow precipitate | |
Sulfate, SO42- |
Add BaCl2 and dilute HCl |
White precipitate |
8.3.6 Instrumental methods
State the adv of using instrumental methods compared with chemical tests (1)
- Accurate (machines can be more accurate than humans)
- Sensitive (only a small amount of sample is needed)
- Rapid (the information can be found very quickly)
8.3.7 Flame emission spectroscopy
Name one instrumental method used to identify elements or compounds (1)
- Atomic absorption (/emission) spectroscopy
Why would use atomic absorption spectroscopy instead of flame test?
- In flame test, 2 different colours mask each other (esp in low concentration)
- AES separates out individual colours more accurately
- Quicker
- Use a small amount of sample
- More sensitive / accurate / precise
Flame emission spectroscopy
- A sample of metal ion in solution is placed into a flame
- The light given out is then passed through a spectroscope
- Spectroscope converts light into a line spectrum
- Positions of lines in spectrum are specific for a given metal ion so can be analysed to identify metal ions in solution & measure their concentration coz lines become more intense at higher concentration
Higher con of ion, greater intensity of light given out